bibtype J - Journal Article
ARLID 0442179
utime 20240103205843.5
mtime 20150724235959.9
SCOPUS 84937107577
WOS 000350939200012
DOI 10.1016/j.saa.2014.12.082
title (primary) (eng) Temperature-related degradation and colour changes of historic paintings containing vivianite
specification
page_count 10 s.
serial
ARLID cav_un_epca*0255117
ISSN 1386-1425
title Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy
volume_id 140
page_num 101-110
publisher
name Elsevier
keyword Degradation
keyword High-temperature X-ray diffraction
keyword Model experiments
keyword Mossbauer spectroscopy
keyword Vivianite
author (primary)
ARLID cav_un_auth*0287834
full_dept (cz) Akademická laboratoř materiálového průzkumu malířských děl (ALMA)
full_dept (eng) Academic Materials Research Laboratory of Painted Artworks (ALMA)
department (cz) ALMA
department (eng) ALMA
full_dept Academic Laboratory of Material Research of Painted Artworks
name1 Čermáková
name2 Zdeňka
institution UACH-T
country CZ
fullinstit Ústav anorganické chemie AV ČR, v. v. i.
author
ARLID cav_un_auth*0245241
full_dept (cz) Akademická laboratoř materiálového průzkumu malířských děl (ALMA)
full_dept Academic Materials Research Laboratory of Painted Artworks (ALMA)
department (cz) ALMA
department ALMA
full_dept Academic Laboratory of Material Research of Painted Artworks
name1 Švarcová
name2 Silvie
institution UACH-T
fullinstit Ústav anorganické chemie AV ČR, v. v. i.
author
ARLID cav_un_auth*0243727
name1 Hradilová
name2 J.
country CZ
author
ARLID cav_un_auth*0102644
full_dept (cz) Akademická laboratoř materiálového průzkumu malířských děl (ALMA)
full_dept Academic Materials Research Laboratory of Painted Artworks (ALMA)
department (cz) ALMA
department ALMA
full_dept Academic Laboratory of Material Research of Painted Artworks
name1 Bezdička
name2 Petr
institution UACH-T
country CZ
fullinstit Ústav anorganické chemie AV ČR, v. v. i.
author
ARLID cav_un_auth*0102684
full_dept (cz) Centrum instrumentálních technik
full_dept Centre of Instrumental Techniques
department (cz) CIT
department CIT
name1 Lančok
name2 Adriana
institution UACH-T
fullinstit Ústav anorganické chemie AV ČR, v. v. i.
author
ARLID cav_un_auth*0299820
name1 Vašutová
name2 V.
country CZ
author
ARLID cav_un_auth*0254045
full_dept (cz) Zpracování obrazové informace
full_dept Department of Image Processing
department (cz) ZOI
department ZOI
full_dept Department of Image Processing
name1 Blažek
name2 Jan
institution UTIA-B
fullinstit Ústav teorie informace a automatizace AV ČR, v. v. i.
author
ARLID cav_un_auth*0102665
full_dept (cz) Akademická laboratoř materiálového průzkumu malířských děl (ALMA)
full_dept Academic Materials Research Laboratory of Painted Artworks (ALMA)
department (cz) ALMA
department ALMA
full_dept Academic Laboratory of Material Research of Painted Artworks
name1 Hradil
name2 David
institution UACH-T
country CZ
fullinstit Ústav anorganické chemie AV ČR, v. v. i.
cas_special
project
ARLID cav_un_auth*0285028
project_id GAP103/12/2211
agency GA ČR
abstract (eng) Temperature-related degradation of pure synthetic as well as partly oxidised natural vivianite has been studied by high-temperature X-ray diffraction (HT-XRD) covering the whole extent of the temperature-related stability of its structure. While temperatures around 70°C are already damaging to vivianite, exposition to 160°C results in complete amorphisation of both the vivianite and its oxidation products. As indicated by Mossbauer spectroscopy, temperature-induced oxidation of vivianite starts at 90°C. To study the occurring structural as well as accompanying colour changes in more detail, model vivianite paint layer samples with different historic binders were prepared and subjected to increased temperatures. Exposition to 80°C caused pronounced colour changes of all the samples: ground natural blue vivianite became grey - a colour change which has been described in actual works of art. Regarding the binders, the oil seemed to facilitate the transfer of heat to vivianite's grains. To simulate conditions of conservation treatment under which the painting is exposed to increased temperatures, oil-on-canvas mock-ups with vivianite were prepared and relined in a traditional way using iron. The treatment affected preferentially larger grains of vivianite; the micro-samples documented their change to grey, and their Raman spectra showed the change from vivianite to metavivianite.
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FORD0 10000
FORD1 10400
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inst_support RVO:61388980
inst_support RVO:67985556
permalink http://hdl.handle.net/11104/0245068
mrcbC64 1 Academic Laboratory of Material Research of Painted Artworks UACH-T 10406 CHEMISTRY, ANALYTICAL
confidential S
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arlyear 2015
mrcbTft \nSoubory v repozitáři: 0442179.pdf
mrcbU14 84937107577 SCOPUS
mrcbU24 25589392 PUBMED
mrcbU34 000350939200012 WOS
mrcbU63 cav_un_epca*0255117 Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy 1386-1425 1873-3557 Roč. 140 APR 2015 101 110 Elsevier